Williams, now 48, was discovered blameworthy of the August 1998 murder of Lisha Gayle, 42, at home in St Louis. He was indicted and condemned to death three years after the fact.
He is planned to be killed by deadly infusion at 6pm on Tuesday (12am GMT).
Be that as it may, new confirmation recommends Williams might be honest, as DNA found on the blade used to murder Ms Gayle does not coordinate his.
Prosecutors assert Williams was burgling his casualty’s home when she found him and he wounded her over and over. He has constantly kept up his guiltlessness.
Williams’ legal counselors have now asked the US Supreme Court to intercede in an edgy last offer to stop his execution. They are additionally speaking to Missouri’s Republican senator, Eric Greitens, to give him forgiveness.
His lawful group says innovation not accessible amid the underlying examination demonstrates DNA found on the murder weapon coordinates that of an obscure male and not Williams.
His legal advisor, Kent Gimpson, disclosed to Al Jazeera: “We appealed to the court to take a gander at the new confirmation on August fourteenth, and under 24 hours after the fact they chose in light of the court documents that the execution ought to proceed in any case. This is remarkable.
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Williams’ supporters additionally feature the racial disparity in the US that implies dark respondents are significantly more prone to be condemned to death than white litigants, particularly if the casualty is white, as Ms Gayle might have been.
The pool of conceivable members of the jury in Williams’ trial included seven African Americas yet everything except one were obstructed by the arraignment, leaving a jury that comprised of 11 white individuals and only one dark one, in spite of half of St Louis tenants being dark.